Nomenclature and Isomerism (New Functional Groups)
0 Pages | Leaving School | 04/05/2024

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New Functional Groups


Compound type Group structure Example
Carboxylate salt Soaps
Acyl choride Ethanoyl Chloride
Acid anhydride Ethanoic Anhydride
Amide Ethanamide
Ester Ethyl Ethanoate

You should also be aware of a few other amine and related molecules

Molecule Group structure Example
Secondary amine Dimethylamine
Tertiary amine Trimethylamine
Alkyl ammonium salt Benzalkonium Chloride

Nomenclature of new groups

Compound/molecule Suffix Prefix Additional notes Example
Carboxylate salts -anoate The cation is first Sodium methanoate
Acyl chlorides -anoyl chloride No numbering is needed Ethanoyl chloride
Acid anhydrides -anoic or aklyl Same alkyl group: ethanoic anhydrideDifferent alkyl groups: methanoic ethanoic anhydride
Amides -anamide No numbering is needed Propanamide
Esters -anoate alkyl- Methyl methanoate
N-substituted amides -anamide N-alkyl- N-ethyl ethanamide
Primary amines -ane amino- Amino should be preceded by the number 2-aminopropane
Secondary amines -ane N-alkyl- The longest chain is name after the suffix N-methyl, 2-aminopropane
Tertiary amines -ane N-alkyl- The longest chain is name after the suffix N-methyl, N-ethyl, 1-aminopropane
Alkylammonium salts -ammonium chloride They are either primary, secondary, tertiary or quaternary Dimethyldiethylammonium chloride

Nomenclature of Compounds containing more than one Functional Group

A Level Chemistry – A lot of organic compounds are composed of more than one functional group. These compounds are more complicated to name but you will only need to be aware of a few of these combinations. For A2 Chemistry you should be particularly familiar with amino acids and hydroxynitriles.

Functional groups Prefix Additional notes Examples
One is an amine or a haloalkane Simply add the necessary prefix 3-aminopropanoic acid

3-chlorobutan-2-olOne is an alcohol and the other a nitrate or contains a C=O bondThe alcohol group: hydroxy- 2-hydroxypropanoic acidOne is an alcohol and the other anything but an amine or haloalkane The -an part is replaced by -en and the position of the alkene is specifiedBut-1-en-4-ol

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